HIGHLY ENANTIOSELECTIVE IMINO PINACOL COUPLING LEADING TO THE SYNTHESIS OF 1,2-DIPHENYLETHYLENEDIAMINE DERIVATIVES

被引:60
作者
SHIMIZU, M [1 ]
IIDA, T [1 ]
FUJISAWA, T [1 ]
机构
[1] MIE UNIV,DEPT CHEM MAT,TSU,MIE 514,JAPAN
关键词
D O I
10.1246/cl.1995.609
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Enantioselective imino pinacol coupling of p-anisylbenzalimine was promoted by the use of Zn-Cu couple in the presence of (+)-camphorsulfonic acid to give (R,R)-1,2-diphenylethylenediamine derivative in high enantiomeric purity.
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页码:609 / 610
页数:2
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