PARAMAGNETIC OXIDES OF NITROGEN OBSERVED IN A SULFUR-HEXAFLUORIDE MATRIX

被引：28

作者：

MORTON, JR ^{[1
]}

PRESTON, KF ^{[1
]}

STRACH, SJ ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA,DIV CHEM,OTTAWA K1A 0R9,ONTARIO,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 04期

关键词：

D O I：

10.1021/j100467a021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

γ irradiation of a solid solution of nitrogen dioxide in sulfur hexafluoride generates a number of paramagnetic nitrogen oxides which exhibit isotropic EPR spectra at 110 K. The radicals NO2, NO3, and F2NO have been positively identified, and a fourth species, hitherto unknown, is believed to be a radical ion of nitrosyl nitrate, ONONO2±. © 1979 American Chemical Society.

引用

页码：533 / 536

页数：4

共 20 条

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