IONIC-CONDUCTION IN PEO-PERFLUOROSULPHONIMIDE DIVALENT SALT COMPLEXES

被引：9

作者：

ATCHIA, S ^{[1
]}

GORECKI, W ^{[1
]}

ARMAND, M ^{[1
]}

DEROO, D ^{[1
]}

机构：

[1] UNIV JOSEPH FOURIER,SPECTROMETRIE PHYS LAB,F-38401 ST MARTIN DHERES,FRANCE

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 09期

关键词：

POLYMER ELECTROLYTE; PERFLUOROSULPHONIMIDE IONIC CONDUCTION; DIVALENT SALT COMPLEXES; CONDUCTIVITY;

D O I：

10.1016/0013-4686(92)80151-B

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The complexes involving PEO and perfluorosulphonimide (TFSI) salts of divalent metals (lead, nickel and copper) have been studied. Encouraging results have been obtained with the TFSI anion as the conductivities are markedly higher than those involving the same cations with other anions. In addition, these complexes are generally entirely amorphous for compositions n less-than-or-equal-to 12 above room temperature. The plasticizing effect of the TFSI ion is again noticed here.

引用

页码：1743 / 1745

页数：3

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