IDENTIFICATION OF THE TOCOPHEROL-CYCLASE IN THE BLUE-GREEN-ALGAE ANABAENA-VARIABILIS KUTZING (CYANOBACTERIA)

被引：36

作者：

STOCKER, A

RUTTIMANN, A

WOGGON, WD

机构：

[1] UNIV ZURICH,INST ORGAN CHEM,WINTERTHURERSTR 190,CH-8057 ZURICH,SWITZERLAND

[2] F HOFFMANN LA ROCHE & CO LTD,VITAMIN RES & TECHNOL DEV,CH-4002 BASEL,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1993年 / 76卷 / 04期

关键词：

D O I：

10.1002/hlca.19930760429

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Incubation of Spheroplasts of Anabaena variabilis (Cyanobacteria) with 22 the 2,6-O-dimethyl-beta-cyclodextrin complex of 2,3-dimethyl-5-phytylhydroquinone (11), revealed the presence of a hitherto unknown enzyme which catalyzes the cyclization of the substrate 11 to give enantiomerically pure gamma-tocopherol (3) in greater-than-or-equal-to 93 % yield.

引用

页码：1729 / 1738

页数：10

共 32 条

[1] AMATO JS, 1979, SYNTHESIS-STUTTGART, P970
[2] BERGERON R, 1975, J BIOL CHEM, V250, P1223
[3] IS VITAMIN-E THE ONLY LIPID-SOLUBLE, CHAIN-BREAKING ANTIOXIDANT IN HUMAN-BLOOD PLASMA AND ERYTHROCYTE-MEMBRANES
BURTON, GW
JOYCE, A
INGOLD, KU
[J]. ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1983, 221 (01) : 281 - 290
[4] BURTON GW, 1986, ACCOUNTS CHEM RES, V19, P194, DOI 10.1021/ar00127a001
[5] SYNTHESIS OF PILOQUINONE, A METABOLITE OF STREPTOMYCES-PILOSUS ETTLINGER
CRESP, TM
GILES, RGF
SARGENT, MV
BROWN, C
SMITH, DO
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1974, (21): : 2435 - 2447
[6] DEBOER TJ, 1963, ORG SYNTH, V4, P250
[7] DHARLINGUE A, 1985, J BIOL CHEM, V260, P5200
[8] BIS (N,N'-DISALICYLALETHYLENEDIAMINE)-MU-AQUODICOBALT(II) - BIS[N,N'-BIS(ORTHO-HYDROXYBENZYLIDINE)ETHYLENEDIAMINE]-MU-AQUODICOBALT(II)
DIEHL, H
HACH, CC
[J]. INORGANIC SYNTHESES, 1950, 3 : 196 - 201
[9] PURIFICATION OF ISOPENTENYL PYROPHOSPHATE ISOMERASE AND GERANYLGERANYL PYROPHOSPHATE SYNTHASE FROM CAPSICUM CHROMOPLASTS BY AFFINITY-CHROMATOGRAPHY
DOGBO, O
CAMARA, B
[J]. BIOCHIMICA ET BIOPHYSICA ACTA, 1987, 920 (02) : 140 - 148
[10] On the existence of a hitherto unrecognized dietary factor essential for reproduction
Evans, HM
Bishop, KS
[J]. SCIENCE, 1922, 56 : 650 - 651

← 1 2 3 4 →