COORDINATION OF PALLADIUM BY AZO AND RELATED FUNCTIONAL GROUPS

被引：97

作者：

BALCH, AL

PETRIDIS, D

机构：

[1] Department of Chemistry, University of California, Los Angeles

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期

关键词：

D O I：

10.1021/ic50081a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and physical properties of the simple azo complexes trans-(RN═NR)2PdX2 (R = CH3, C6H6; X = Cl, Br) are reported. Infrared and nmr spectral observations indicate that each azo group is coordinated to palladium through a single nitrogen lone pair. Similar complexes of azoxybenzene could not be prepared, but it is possible to deprotonate azoxybenzene to form dichlorobis[2-(phenylazoxy)phenyl]dipalladium(II), 6. The dimer is readily cleaved by organic bases to give monomeric species. The preparation and properties of (C6H5NO)2PdCl2 are reported. © 1969, American Chemical Society. All rights reserved.

引用

页码：2247 / &

共 28 条

[1] THE CRYSTAL STRUCTURE OF THE CUPROUS CHLORIDE AZOMETHANE COMPLEX [J].