REACTIONS OF SHOCK-HEATED CARBON DISULFIDE-ARGON MIXTURES .I. LIGHT EMISSION

被引：6

作者：

ARNOLD, SJ

KIMBELL, GH

机构：

[1] Canadian Armament Research and Development Establishment, Centre de Recherches sur les Atomes et Molécules, Québec, Que.

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 11期

关键词：

D O I：

10.1021/j100845a032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The light emission from shock-heated CS2-Ar mixtures varying in composition from 1 to 100% CS2 has been measured as a function of wavelength in the range 3750-8250 A. Measurements of the Arrhenius activation energy indicate that the molecule is excited to the 3Σu+ state. It was not possible to distinguish between a single-step excitation process and a more complex mechanism involving vibrational excitation of the ground state.

引用

页码：3751 / &

共 8 条

[1] LIGHT EMISSION FROM SHOCK-HEATED CARBON DISULFIDE-ARGON MIXTURES
ARNOLD, SJ
BROWNLEE, WG
KIMBELL, GH
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12) : 4344 - &
[2] SHOCK-TUBE STUDY OF CARBON DIOXIDE DISSOCIATION RATE
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[3] ZEEMAN EFFECT + ROTATIONAL ANALYSES OF NEAR-ULTRAVIOLET BANDS OF CS2
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[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (02) : 357 - &
[4] SHOCK-TUBE STUDY OF KINETICS OF DECOMPOSITION OF CARBON DISULPHIDE
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[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1964, 279 (1376) : 313 - +
[5] NEAR-ULTRAVIOLET ABSORPTION SPECTRUM OF CS2
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[J]. CANADIAN JOURNAL OF PHYSICS, 1963, 41 (12) : 2034 - &
[6] THE LOWER EXCITED STATES OF SOME SIMPLE MOLECULES
MULLIKEN, RS
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1958, 36 (01): : 10 - 23
[7] UNIMOLEKULARER ZERFALL VON CS2 IN STOSSWELLEN
OLSCHEWSKI, HA
TROE, J
WAGNER, HG
[J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1965, 45 (5-6): : 329 - +
[8] The absorption spectra of sulphur dioxide and carbon disulphide in the vacuum ultra-violet
Price, WC
Simpson, DM
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1938, 165 (A921) : 0272 - 0291

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