MOLECULAR MODULATION STUDY OF THE REACTION OF HG(63PO) WITH CL-2

被引：11

作者：

WODARCZYK, FJ

HARKER, AB

机构：

[1] Rockwell International Science Center, Thousand Oaks

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 62卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80756-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate of the reactive quenching of metastable Hg(6 3P0) atoms by molecular chlorine was determined by phase-sensitive modulation spectroscopy to be (1.0 ± 0.2) × 10-10 cm3 molecule-1 s-1, corresponding to a quenching cross section of 28 Å2. Mechanistic studies showed that HgCl in the (B2Σ+ 1 2) state is one of the products of this reaction, being formed in 0.9 ± 0.3% of the reactive collisions. © 1979.

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页码：529 / 533

页数：5

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