EVIDENCE FOR THE INVOLVEMENT OF CHROMIUM(II) AS AN INTERMEDIATE IN THE REDUCTION OF CHROMIUM(VI) TO CHROMIUM(III) BY FORMALDEHYDE

被引：61

作者：

PEREZBENITO, JF

ARIAS, C

LAMRHARI, D

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 06期

关键词：

D O I：

10.1039/c39920000472

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between chromium(VI) and formaldehyde in aqueous perchloric acid is inhibited by manganese(II) ion, according to the relation k1 = a/(1 + b[Mn2+]) + c; manganese(II) ion and formaldehyde compete to reduce the intermediate Cr(IV), and Cr(II) is an intermediate.

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页码：472 / 474

页数：3

相关论文

共 11 条

[1]

BEATTIE JK, 1972, INORGANIC REACTION 2, P96

[2] CHROMIUM(VI) FORMS A THIOLATE COMPLEX WITH GLUTATHIONE [J].

BRAUER, SL ;

WETTERHAHN, KE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3001-3007

[3] ASSOCIATION OF CHROMIUM(VI) WITH NEPTUNIUM(IV) AND THORIUM(IV) IN PERCHLORATE SOLUTION [J].

BURKHART, MJ ;

THOMPSON, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (09) :2999-&

[4] MECHANISM OF CHROMIC ACID OXIDATIONS .4. OXIDATION OF FORMALDEHYDE BY CHROMIC ACID [J].

CHATTERJI, AC ;

MUKHERJEE, SK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (14) :3600-3604

[5] INVITRO REACTION OF THE CARCINOGEN CHROMATE WITH CELLULAR THIOLS AND CARBOXYLIC-ACIDS [J].

CONNETT, PH ;

WETTERHAHN, KE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (14) :4282-4288

[6] REACTIONS OF CHROMIUM(IV) [J].

HAIGHT, GP ;

HUANG, TJ ;

SHAKHASH.BZ .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1971, 33 (07) :2169-&

[7]

MARCH J, 1985, ADV ORG CHEM, P630

[8] PREPARATION AND REACTIVITY OF THE AQUACHROMIUM(IV) ION [J].

SCOTT, SL ;

BAKAC, A ;

ESPENSON, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) :7787-7788

[9]

STEWART R, 1964, OXIDATION MECHANISMS, P37

[10] THE KINETICS OF THE CHROMIC ACID OXIDATION OF ISOPROPYL ALCOHOL - THE INDUCED OXIDATION OF MANGANOUS ION [J].

WATANABE, W ;

WESTHEIMER, FH .

JOURNAL OF CHEMICAL PHYSICS, 1949, 17 (01) :61-70