REACTION OF SOME 2-(N-TRIMETHYLSILYL)AMINO-1,3,2-OXAZAPHOSPHOLANES WITH BENZALDEHYDE

被引：1

作者：

PUDOVIK, MA

KIBARDINA, LK

MEDVEDEVA, MD

PUDOVIK, AN

机构：

[1] A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 05期

关键词：

D O I：

10.1007/BF00963321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 2-(N-trimethylsilyl)amido-1,3,2-oxazaphospholanes with benzaldehyde proceeds on the phosphorus atom with migration of the trimethylsilyl group onto the carbonyl oxygen and the formation of cyclic imidophosphonates. The latter, depending on the character of the substituent at the imide nitrogen atom and the conditions of carrying out the reaction, can be converted into phosphonates or decomposed into the original reactants. © 1979 Plenum Publishing Corporation.

引用

页码：1022 / 1025

页数：4