COUPLING REACTIONS OF DITERPENOID ETA-2-TETRACARBONYLMANGANESE COMPLEXES WITH ALKYNES

被引：45

作者：

CAMBIE, RC ^{[1
]}

METZLER, MR ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 429卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)83317-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of tetracarbonylmanganese complexes derived from podocarpic acid (1) have been coupled with acetylene or diphenylacetylene to give steroidal analogues in high yield. Several modes of activating these manganese complexes towards coupling reactions were investigated, including oxidative decarbonylation at room temperature and thermal promotion.

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页码：41 / 57

页数：17

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