OPTICAL SPECTROSCOPY OF HIGHLY ORDERED POLY(P-PHENYLENE VINYLENE)

被引：258

作者：

PICHLER, K ^{[1
]}

HALLIDAY, DA ^{[1
]}

BRADLEY, DDC ^{[1
]}

BURN, PL ^{[1
]}

FRIEND, RH ^{[1
]}

HOLMES, AB ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 1993年 / 5卷 / 38期

关键词：

D O I：

10.1088/0953-8984/5/38/011

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We report a study of the photophysical properties of poly(p-phenylene vinylene), PPV, prepared in a way that gives an especially high degree of intrachain order. Optical absorption, photoluminescence, photoinduced absorption, and photoconductivity excitation spectra are presented and compared to data reported for less well ordered PPV. Spectral red shifts, sharpening of spectral lines, and a transfer of oscillator strength into the vibronic ground states of the electronic transitions are observed. Photoinduced absorption due to long-lived charged excitations, previously reported for less ordered PPV. could not be detected in this material. Photoconductivity excitation spectra show a steep rise at the absorption edge with no appreciable offset between the onsets for photoconduction and absorption. A very slow photocurrent component is observed, which we associate with the trapping and subsequent thermal release of photocarriers.

引用

页码：7155 / 7172

页数：18

共 64 条

[1]

ANTONIADIS H, COMMUNICATION

[2]

Baeriswyl D., 1992, SPRINGER SERIES SOLI, V102

[3] EXCITON VERSUS BAND DESCRIPTION OF THE ABSORPTION, LUMINESCENCE AND ELECTROABSORPTION OF POLY(PHENYLPHENYLENEVINYLENE) AND POLY(DODECYLTHIOPHENE) [J].