NANODISPERSED COBALT PARTICLES IN A THERMOLYSED POLY(ACRYLONITRILE) MATRIX

被引：35

作者：

BRONSTEIN, LM ^{[1
]}

MIRZOEVA, ES ^{[1
]}

VALETSKY, PM ^{[1
]}

SOLODOVNIKOV, SP ^{[1
]}

机构：

[1] PRINCETON UNIV,DEPT CHEM ENGN,PRINCETON,NJ 08544

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 08期

关键词：

D O I：

10.1039/jm9950501197

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation of nanodispersed (D approximate to 10 nm) beta-Co particles in a polymeric matrix is demonstrated, by thermolysing films of poly(acrylonitrile) containing homogeneously distributed [Co(dimethylformamide)(6)(2+)][Co(CO)(4)(-)](2). Super-paramagnetic behaviour is evident in these particles as determined by ferromagnetic resonance. Small-angle X-ray scattering is used to quantify the average particle size. The size of the Co particles can be controlled either by varying the thermolysis conditions or the loading of Co in the films prior to thermolysis.

引用

页码：1197 / 1201

页数：5

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