CONFORMATIONAL STUDIES AND STEREOCHEMICAL ASSIGNMENTS OF THE LACTARANE SESQUITERPENES FUROSCROBICULIN-D AND BLENNIN-D

被引：6

作者：

GARLASCHELLI, L

TOMA, L

VIDARI, G

COLOMBO, D

机构：

[1] UNIV PAVIA,DIPARTIMENTO CHIM ORGAN,I-27100 PAVIA,ITALY

[2] UNIV MILAN,DIPARTIMENTO CHIM & BIOCHIM MED,I-20133 MILAN,ITALY

来源：

TETRAHEDRON | 1994年 / 50卷 / 04期

关键词：

D O I：

10.1016/S0040-4020(01)80832-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two lactarane sesquiterpenes, furoscrobiculin D and blennin D, previously isolated from the mushrooms Lactarius scrobiculatus and Lactarius blennius, respectively, have been submitted to conformational analysis by molecular mechanics. The results of the molecular modeling were related to the observed H-1 NMR data and allowed to assign stereostructure 4 to furoscrobiculin D, correcting the previous assignment 1, and stereostructure 5 to blennin D, confirming the previous assignment.

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页码：1211 / 1216

页数：6

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