SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE BENT NITROSYL ORGANOMETALLIC COMPLEX [NBU4][PT(C6CL5)2CL2(NO)]

被引：7

作者：

FORNIES, J

MENJON, B

SANZCARRILLO, RM

TOMAS, M

机构：

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 04期

关键词：

PLATINUM COMPLEXES; 5-COORDINATE; NITROSYL COMPLEXES;

D O I：

10.1002/cber.19941270412

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex has been prepared in 36% yield by reaction of [NBu4]2[trans-Pt(C6Cl5)2Cl2] with NOClO4 (1:1) in CH2Cl2. The anion exhibits an almost tetragonal-pyramidal geometry (X-ray analysis), the platinum atom being virtually located in the basal plane and the NO ligand occupying the apical position. The Pt-N-0 unit is bent [119.5(8)-degrees).

引用

页码：651 / 652

页数：2

共 28 条

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