SYNTHESIS OF TETRATHIAFULVALENE POLYMERS

被引：69

作者：

FRENZEL, S ^{[1
]}

ARNDT, S ^{[1
]}

GREGORIOUS, RM ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,D-55128 MAINZ,GERMANY

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 10期

关键词：

D O I：

10.1039/jm9950501529

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Several main-chain and side-chain tetrathiafulvalene (TTF) polymers have been synthesized combining the unique properties of high molecular weight polymers, such as processability, with the outstanding electron donating properties of TTF systems. Doping of polyurethane with TCNQF(4) leads to a free-standing, processable film exhibiting a moderately high electrical conductivity of 8 x 10(-4) S cm(-1), which is comparable to iodine-doped non-ordered polythiophene. The synthesis of a fully conjugated, planar and sulfur-rich TTF polymer, which should increase the dimensionality of the conduction process in the doped state, is presented.

引用

页码：1529 / 1537

页数：9

共 28 条

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