A SCHIFF-BASE P-TERT-BUTYLCALIX[4]ARENE - SYNTHESIS AND METAL-ION COMPLEXATION

被引：28

作者：

SEANGPRASERTKIJ, R ^{[1
]}

ASFARI, Z ^{[1
]}

ARNAUD, F ^{[1
]}

WEISS, J ^{[1
]}

VICENS, J ^{[1
]}

机构：

[1] EHICS,CNRS,URA 405,1 RUE BLAISE PASCAL,F-67009 STRASBOURG,FRANCE

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1992年 / 14卷 / 02期

关键词：

1,3-BRIDGED CALIX[4]ARENE; SCHIFF-BASE; ALKALINE AND ALKALINE-EARTH CATIONS; TRANSITION METALS; STABILITY CONSTANTS; BIPHASIC TRANSFER;

D O I：

10.1007/BF01029661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication describes the synthesis of Schiff base calix[4]arene (1) in which the Schiff base unit bridges two opposite hydroxy groups of p-tert-butylcalix[4]arene. The synthesis of (1) has been achieved by refluxing in acetonitrile-methanol the appropriate 1,3-dicarbaldehyde-p-tert-butylcalix[4]arene (4) with 1,3-diaminopropane. The yield of the reaction is 19%. Ligand (1) possesses a compartment containing two nitrogen atoms, four ether-type oxygen atoms, and two ionizable hydroxy groups likely to complex metal cations.

引用

页码：141 / 147

页数：7

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