FACILE SYNTHESIS AND STRUCTURE OF THE MN-IV-MN-IV DINUCLEAR COMPLEX [MN(SALPN)O](2)(DMSO)(2)[SALPNH(2)=N,N'-BIS(SALICYLIDENE)-1,3-DIAMINOPROPANE]

被引：14

作者：

AURANGZEB, N ^{[1
]}

MCAULIFFE, CA ^{[1
]}

PRITCHARD, RG ^{[1
]}

WATKINSON, M ^{[1
]}

BERMEJO, M ^{[1
]}

GARCIADEIBE, A ^{[1
]}

SOUSA, A ^{[1
]}

机构：

[1] UNIV SANTIAGO COMPOSTELA,DEPT QUIM INORGAN,SANTIAGO,SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷 / 11期

关键词：

D O I：

10.1107/S010827019201326X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Mn-IV dimer [Mn(salpn)O](2), di-mu-oxo-bis({2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato-N,N',O,O'}manganese(IV)), has been produced as the DMSO adduct by the facile air oxidation of the complex {[Mn-III(salpn)(H2O)](ClO4)}(2) in DMSO, giving dark-green crystals. Both Mn atoms are in approximately octahedral environments made up of the tetradentate Schiff base salpn and two mu-oxo O atoms, which are both cis [Mn-O 1.804(5) and Mn-O' 1.832(5) Angstrom].

引用

页码：1945 / 1947

页数：3

共 15 条

[1] A NOVEL MANGANESE(III) DIMER WITH AN EXTREMELY LONG MN-MN DISTANCE [J].

ASHMAWY, FM ;

BEAGLEY, B ;

MCAULIFFE, CA ;

PARISH, RVD ;

PRITCHARD, RG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (13) :936-937

[2] WATER PHOTOLYSIS .1. THE PHOTOLYSIS OF COORDINATED WATER IN [(MNL-(H2O))2][CLO4]2 (L = DIANION OF TETRADENTATE O2N2-DONOR SCHIFF-BASES) - A MODEL FOR THE MANGANESE SITE IN PHOTOSYSTEM-II OF GREEN PLANT PHOTOSYNTHESIS [J].

ASHMAWY, FM ;

MCAULIFFE, CA ;

PARISH, RV ;

TAMES, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (07) :1391-1397

[3]

BEURSKENS PT, 1984, 19841 CRYST LAB TECH

[4] STRUCTURALLY DIVERSE MANGANESE(III) SCHIFF-BASE COMPLEXES - CHAINS, DIMERS, AND CAGES [J].

BONADIES, JA ;

KIRK, ML ;

LAH, MS ;

KESSISSOGLOU, DP ;

HATFIELD, WE ;

PECORARO, VL .

INORGANIC CHEMISTRY, 1989, 28 (11) :2037-2044

[5]

DISMUKES GC, 1986, MANGANESE METABOLISM, pCH16

[6] MONONUCLEAR MANGANESE(IV) IN TRIDENTATE ONO COORDINATION - SYNTHESIS, STRUCTURE, AND REDOX REGULATION VIA OXYGEN DONOR VARIATION [J].

DUTTA, S ;

BASU, P ;

CHAKRAVORTY, A .

INORGANIC CHEMISTRY, 1991, 30 (21) :4031-4037

[7] THE MANGANESE SITE OF THE PHOTOSYNTHETIC WATER-SPLITTING ENZYME [J].

GEORGE, GN ;

PRINCE, RC ;

CRAMER, SP .

SCIENCE, 1989, 243 (4892) :789-791

[8] MITHRIL - AN INTEGRATED DIRECT-METHODS COMPUTER-PROGRAM [J].

GILMORE, CJ .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1984, 17 (FEB) :42-46

[9] SYNTHESIS, STRUCTURE, AND PROPERTIES OF [MN(SALPN)(ETOH)2](CLO4) AND ITS AEROBIC OXIDATION-PRODUCT [MN(SALPN)O]2 [J].

GOHDES, JW ;

ARMSTRONG, WH .

INORGANIC CHEMISTRY, 1992, 31 (03) :368-373

[10]

HELLIWELL M, 1991, UNPUB

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