EMBRITTLEMENT AND STRESS CRACKING OF POLYETHYLENE BY FUMING NITRIC ACID

被引:12
作者
HINTON, T
KELLER, A
机构
[1] H. H. Wills Physics Laboratory, Bristol University
关键词
D O I
10.1002/app.1969.070130413
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Oxidative embrittlement and stress cracking of high‐density polyethylene has been studied by using fuming nitric acid at 60°C as the oxidative agent. Oxidative stress cracking was found to be insensitive to changes in molecular weight in contrast to environmental stress cracking in a surface‐active medium. The oxidative attack was found to be influenced by the surface crystalline texture of the polyethylene. Oriented polyethylene showed an increased resistance to oxidative embrittlement and stress cracking, the mode of failure being dependent upon the prior annealing treatment. Copyright © 1969 John Wiley & Sons, Inc.
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页码:745 / &
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