HEXAGONAL INDIUM TUNGSTEN BRONZE

被引:23
作者
BOUCHARD, RJ
GILLSON, JL
机构
[1] Central Research Department, Experimental Station, E. I. du Pont de Nemours and Company, Wilmington
关键词
D O I
10.1021/ic50063a025
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The electrical resistivity of single crystals of hexagonal InxWO3 (x = 0.21-0.27) has been measured both perpendicular to and parallel with the c axis. Nearly isotropic metallic behavior was found. Seebeck voltages were small and negative, while magnetic susceptibility measurements showed isotropic diamagnetism. These results are consistent with covalent t2g-pπ bonding and the formation of a π* band. © 1968, American Chemical Society. All rights reserved.
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页码:969 / &
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