MESOMORPHIC PROPERTIES OF BROMO AND CYANO SUBSTITUTED DIARYLETHANES

被引:15
作者
TINH, NH
ZANN, A
DUBOIS, JC
机构
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1979年 / 53卷 / 1-2期
关键词
D O I
10.1080/00268947908083981
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two homologous series of diarylethanes: 1-(4-alkoxy or alkyl-benzoyloxyphenyl)-2-(4 prime -bromo or cyanophenyl) ethanes (series I) and 1-(4-alkoxy 3-bromo or cyanobenzoyloxyphenyl)-2-(4 prime -pentylphenyl) ethanes (series II) have been synthesized. The influence of the bromo or cyano group, in the meta or para position, on the mesomorphic range and the clearing point, is studied. In the series I, the bromo group induces a smectic polymorphism, whereas the cyano group induces nematic mesophases. In the series II, the larger the meta substituant, the lower the clearing point.
引用
收藏
页码:29 / &
相关论文
共 20 条
[1]  
COATES D, 1976, J CHEM SOC P2, P864
[2]  
DEUTSCHER HJ, 1977, Z CHEM, V17, P64
[3]  
DUBOIS JC, UNPUBLISHED
[4]  
DUBOIS JC, 1977, MOL CRYST LIQ CRYST, V42, P139
[5]  
DUBOIS JC, 1976, J PHYS-PARIS, V37, P35, DOI DOI 10.1051/JPHYSCOL:1976305
[6]  
EIDENSCHINK R, 1977, ANGEW CHEM, V89, P103, DOI DOI 10.1002/ANGE.19770890208
[7]  
GRAY GW, 1953, J CHEM SOC, P4179
[8]  
Gray GW., 1974, LIQ CRYST ORDERED FL, V2, P617, DOI [10.1007/978-1-4684-2727-1_55, DOI 10.1007/978-1-4684-2727-1_55]
[9]  
JONES FB, 1975, J PHYSICS C, V36, P413
[10]  
KATAMURA T, 1977, Patent No. 116436