ABSORPTION-SPECTRA OF THE RADICAL IONS OF QUINONES - A PULSE-RADIOLYSIS STUDY

被引：41

作者：

MAYER, J

KRASIUKIANIS, R

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 18期

关键词：

D O I：

10.1039/ft9918702943

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation of quinone radical ions was observed at room temperature using pulse radiolysis. The following quinones were investigated: p-benzoquinone, p-naphthoquinone, 5,8-dihydroxy-1,4-naphthoquinone, anthraquinone and 1,4-dihydroxyanthraquinone. The radial cations were produced in freon-113 solutions and the radical anions were produced in methanol solutions. The absorption spectra of the radical ions were found in the near-UV-VIS range. The spectra of the radical cations were blue shifted compared with the spectra of the corresponding radical anions.

引用

收藏

页码：2943 / 2947

页数：5

相关论文

共 17 条

[1] ELECTRONIC-STRUCTURES OF PARA-BENZOQUINONE AND CYCLOHEXANE-1,4-DIONE RADICAL CATIONS - ELECTRON-SPIN RESONANCE STUDY [J].

CHANDRA, H ;

PORTWOOD, L ;

SYMONS, MCR .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :1801-1807

[2] ROLE OF BINDING-ENERGIES IN A-.B AND A.B- COMPLEXES IN THE KINETICS OF GAS-PHASE ELECTRON-TRANSFER REACTIONS - A-+B=A+B- INVOLVING PERFLUORO COMPOUNDS - SF6, C6F11CF3, C6F6 [J].

CHOWDHURY, S ;

KEBARLE, P .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (09) :4989-4994

[3] CHEMICALLY-INDUCED DYNAMIC ELECTRON POLARIZATION (CIDEP) OF SOME SULFUR-CONTAINING CATION RADICALS - EVIDENCE OF THE CHARGE-TRANSFER PROCESSES BETWEEN QUINONE CATION RADICALS AND SULFUR HETEROCYCLIC-COMPOUNDS [J].

DEPEW, MC ;

ZHONGLI, L ;

WAN, JKS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (08) :2480-2481

[4] ELECTRON-AFFINITY OF SF6 AND PERFLUOROMETHYLCYCLOHEXANE - THE UNUSUAL KINETICS OF ELECTRON-TRANSFER REACTIONS A-+B=A+B-, WHERE A=SF6 OR PERFLUORINATED CYCLO-ALKANES [J].

GRIMSRUD, EP ;

CHOWDHURY, S ;

KEBARLE, P .

JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (03) :1059-1068

[5] THE SHORT-LIVED IONIC SPECIES OF FREON-113 (CFCL2CF2CL) - A PULSE-RADIOLYSIS STUDY [J].

HURNI, B ;

BUHLER, RE .

RADIATION PHYSICS AND CHEMISTRY, 1980, 15 (2-3) :231-241

[6]

JONES RAY, PHYSICAL MECHANISTIC, P125

[7] PULSE-RADIOLYSIS SYSTEM BASED ON ELU-6E LINAC [J].

KAROLCZAK, S ;

HODYR, K ;

LUBIS, R ;

KROH, J .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1986, 101 (02) :177-188

[8]

KAROLCZAK S, UNPUB

[9] REDUCTION OF THE NAPHTHAZARIN MOLECULE AS STUDIED BY PULSE-RADIOLYSIS .1. ADDITION OF A SINGLE ELECTRON [J].

LAND, EJ ;

MUKHERJEE, T ;

SWALLOW, AJ ;

BRUCE, JM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 :391-404

[10] GENERATION OF QUINONE CATION RADICALS VIA PHOTOINDUCED ELECTRON-TRANSFER - ELECTRON-SPIN-RESONANCE EVIDENCE [J].

LIU, ZL ;

WU, LM ;

LIU, YC .

MAGNETIC RESONANCE IN CHEMISTRY, 1988, 26 (07) :577-580