RUTHENIUM-CATALYZED CYTOCHROME-P-450 TYPE OXIDATION OF ALKANES WITH ALKYL HYDROPEROXIDES

被引：92

作者：

MURAHASHI, S ^{[1
]}

ODA, Y ^{[1
]}

NAOTA, T ^{[1
]}

KUWABARA, T ^{[1
]}

机构：

[1] SUMITOMO CHEM CO LTD,ORGAN SYNTH RES LAB,TAKATSUKI,OSAKA 569,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)91779-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ruthenium-catalyzed oxidation of alkanes with t-butyl hydroperoxide under mild conditions gives the corresponding ketones and alcohols highly efficiently. Kinetic study revealed that the reaction involves hydrogen abstraction of oxoruthenium species.

引用

页码：1299 / 1302

页数：4

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