RUTHENIUM-CATALYZED CYTOCHROME-P-450 TYPE OXIDATION OF ALKANES WITH ALKYL HYDROPEROXIDES

被引:92
作者
MURAHASHI, S [1 ]
ODA, Y [1 ]
NAOTA, T [1 ]
KUWABARA, T [1 ]
机构
[1] SUMITOMO CHEM CO LTD,ORGAN SYNTH RES LAB,TAKATSUKI,OSAKA 569,JAPAN
关键词
D O I
10.1016/S0040-4039(00)91779-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The ruthenium-catalyzed oxidation of alkanes with t-butyl hydroperoxide under mild conditions gives the corresponding ketones and alcohols highly efficiently. Kinetic study revealed that the reaction involves hydrogen abstraction of oxoruthenium species.
引用
收藏
页码:1299 / 1302
页数:4
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