CALORIMETRIC INVESTIGATION OF AN EXOTHERMIC REACTION - KINETIC AND HEAT-FLOW MODELING

被引：23

作者：

LANDAU, RN ^{[1
]}

BLACKMOND, DG ^{[1
]}

TUNG, HH ^{[1
]}

机构：

[1] MERCK & CO INC,MERCK RES LABS,RAHWAY,NJ 07065

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1994年 / 33卷 / 04期

关键词：

D O I：

10.1021/ie00028a005

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Utilizing an automated laboratory reaction calorimeter, an energetic reaction was investigated to determine feasible pilot plant operating conditions. The calorimetric data led to kinetic parameters and a predictive heat flow model which allowed simulations of the required pilot plant jacket temperature profiles. On the basis of these profiles, several feasible and safe operating conditions were determined. This study demonstrates the power of calorimetry as it relates to process design and scale-up of batch and semibatch processes.

引用

页码：814 / 820

页数：7

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