SYNTHESIS, FLUXIONAL BEHAVIOR AND X-RAY CRYSTAL-STRUCTURE OF [FE(CO)3(MU-ETA-3-ETA-2-C7H7)PD(ETA-5-C5H5)]

被引：7

作者：

AIROLDI, M

DEGANELLO, G

GENNARO, G

MORET, M

SIRONI, A

机构：

[1] UNIV PALERMO,DIPARTIMENTO CHIM INORGAN,VIA ARCHIRAFI 26,I-90123 PALERMO,ITALY

[2] UNIV MILAN,IST CHIM STRUTTURIST INORGAN,I-20133 MILAN,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of K[(eta-3-C7H7)Fe(CO)3] with [(1,5-eta-4-C8H12)Pd(eta-5-C5H5)]BF4 gives the title compound which is the first case of a bridging cycloheptatrienyl metal-metal bonded complex having an uncoordinated double bond in the ring and detectable low-temperature limiting H-1 and C-13 NMR spectra.

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页码：850 / 851

页数：2

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