PREPARATION AND REACTIONS OF 1,4-DIALKOXYCARBONYL-1,4-DIALKYL-2-TETRAZENES

被引：26

作者：

WADSWORTH, WS

机构：

[1] Department of Chemistry, South Dakota State University, Brookings

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 10期

关键词：

D O I：

10.1021/jo01262a043

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of 1,4-dialkoxy carbonyl-1,4-dialkyl-2-tetrazenes have been prepared by the bromine oxidation of 1-alkoxycarbonyl-l-alkylhydrazines. The tetrazenes which have a trans configuration react with nucleophiles to give products arising from carbon-nitrogen bond scission. One of the products, 1,4-dimethyltetrazolinone, although thermally stable, undergoes solvent assisted photodecompositions to give isoureas. © 1969, American Chemical Society. All rights reserved.

引用

页码：2994 / +

页数：1

共 19 条

[1] PHOTOCHEMISTRY OF ORGANIC NITROGEN COMPOUNDS .4. PHOTOLYSIS OF 4-ALKYLIDENE-1-PYRAZOLINES - A POSSIBLE ROUTE TO TRIS-METHYLENEMETHYL DIRADICALS [J].