Magnetic susceptibility anisotropy and molecular quadrupole moment of fluoroacetylene

被引：16

作者：

Shoemaker, R. L. ^{[1
]}

Flygare, W. H. ^{[1
]}

机构：

[1] Univ Illinois, Noyes Chem Lab, Urbana, IL 61801 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 08期

关键词：

D O I：

10.1016/0009-2614(63)80030-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular Zeeman effect has been observed in FC CH under high resolution. The data yield the molecular g-value of g(perpendicular to) = - 0.0077 +/- 0.0002 and magnetic susceptibilitv anisotropy of x(perpendicular to) - x(parallel to) = (0.861 approximate to +/- 0.018) x 10(-29) erg/G(2). The combination of these two results gives the molecular quadrupole moment in FC CH of Q(parallel to) = (3.96 +/- 0.14) x 10(-26) esu cm(2).

引用

页码：610 / 612

页数：3

共 10 条

[1] QUADRUPOLE MOMENTS OF SOME SIMPLE MOLECULES [J].

BUCKINGHAM, AD ;

DISCH, RL ;

DUNMUR, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (12) :3104-+

[2] MOLECULAR QUADRUPOLE MOMENTS [J].

BUCKINGHAM, AD .

QUARTERLY REVIEWS, 1959, 13 (03) :183-214

[3] ROTATIONAL MAGNETIC MOMENTS [J].

CEDERBERG, JW ;

RAMSEY, NF ;

ANDERSON, CH .

PHYSICAL REVIEW A-GENERAL PHYSICS, 1964, 136 (4A) :A960-&

[4]

FLYGARE WH, 1969, IN PRESS J CHEM PHYS, V50

[5]

FLYGARE WH, 1969, IN PRESS J CHEM PHYS, V49

[6]

HUTTNER W, 1968, J CHEM PHYS, V48, P1206

[7]

HUTTNER W, 1967, J CHEM PHYS, V47, P4137

[8] FLUOROACETYLENE [J].

MIDDLETON, WJ ;

SHARKEY, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (04) :803-804

[9] STRUCTURAL STUDIES OF LINEAR MOLECULES BY MICROWAVE SPECTROSCOPY [J].

TYLE, JK ;

SHERIDAN, J .

TRANSACTIONS OF THE FARADAY SOCIETY, 1963, 59 (492) :2661-&

[10] MOLECULAR G VALUE MAGNETIC PROPERTIES AND GROUND-STATE ELECTRONIC STRUCTURE OF FLUOROACETYLENE [J].

WEISS, VW ;

TODD, HD ;

LO, MK ;

GUTOWSKY, HS ;

FLYGARE, WH .

JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (10) :4021-&

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