Low-field and zero-field optical detection of magnetic resonance in a (3)n pi* state: Pyrazine

被引：51

作者：

Cheng, Liang-Tsai ^{[1
]}

Kwiram, Alvin L. ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem, Cambridge, MA 02138 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 4卷 / 07期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(69)85012-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The zero-field parameters for the lowest n-pi* triplet state of pyrazine are determined using optical detection of the magnetic resonance in zero magnetic field. The values thus obtained are D = +/- 0.33923 +/- 0.00002 cm(-1) and E = +/- 0.00719 +/- 0.00002 cm(-1). The hyperfine splittings due to the mtrogen and hydrogen nuclei are discussed.

引用

页码：457 / 460

页数：4

共 21 条

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