HIGHLY STEREOSELECTIVE DOUBLE MICHAEL CYCLIZATION OF 1-PHENYLSULFINYL AND SULFONYL ANALOGS OF THE NAZAROV REAGENT

被引：20

作者：

SPINO, C ^{[1
]}

DESLONGCHAMPS, P ^{[1
]}

机构：

[1] UNIV SHERBROOKE,FAC SCI,DEPT CHIM,SYNTHESE ORGAN LAB,SHERBROOKE J1K 2R1,QUEBEC,CANADA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(00)94474-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The base-catalyzed double Michael addition of the β-keto sulfoxide 5 with 2-carbomethoxy-2-cyclohexenone (1) proceeds, after elimination of the sulfoxide moiety during chromatography on silica, to give the dehydrodecalin adduct 6 with high stereoselectivity. © 1990.

引用

页码：3969 / 3972

页数：4

共 10 条

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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (14) : 2920 - 2923
[9] DIELS-ALDER REACTIONS OF 2-CARBOMETHOXY-2-CYCLOHEXEN-1-ONE
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[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1988, 66 (12): : 3143 - 3152
[10] RUEL R, TETRAHEDRON LETT

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