STEADY-STATE MICROELECTRODE VOLTAMMETRY AS A ROUTE TO HOMOGENEOUS KINETICS

被引:61
作者
OLDHAM, KB
机构
[1] Electrochemical Laboratories, Trent University
关键词
D O I
10.1016/0022-0728(91)85167-N
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
It is demonstrated that, under propitious circumstances, information concerning the kinetics of homogenous reactions can be gained by studying how features of steady-state voltammograms depend on the size of the voltammetric microelectrode. Applications to CE, EC, ECE and EC' mechanisms are discussed.
引用
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页码:3 / 16
页数:14
相关论文
共 19 条
[1]  
BARD AJ, 1980, ELECTROCHEMICAL METH, pCH11
[2]   STEADY-STATE VOLTAMMETRY [J].
BOND, AM ;
OLDHAM, KB ;
ZOSKI, CG .
ANALYTICA CHIMICA ACTA, 1989, 216 (1-2) :177-230
[3]  
BRETT CMA, 1986, COMPREHENSIVE CHEM K, V26, P411
[4]   SPHERICITY CORRECTIONS IN REVERSIBLE VOLTAMMETRY [J].
BRYDON, GA ;
OLDHAM, KB .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1981, 122 (MAY) :353-357
[5]   THE APPLICATION OF MICROELECTRODES TO THE STUDY OF HOMOGENEOUS PROCESSES COUPLED TO ELECTRODE-REACTIONS [J].
FLEISCHMANN, M ;
LASSERRE, F ;
ROBINSON, J .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 177 (1-2) :115-127
[6]   THE APPLICATION OF MICROELECTRODES TO THE STUDY OF HOMOGENEOUS PROCESSES COUPLED TO ELECTRODE-REACTIONS .1. EC' AND CE REACTIONS [J].
FLEISCHMANN, M ;
LASSERRE, F ;
ROBINSON, J ;
SWAN, D .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 177 (1-2) :97-114
[7]  
Fleischmann M, 1987, ULTRAMICROELECTRODES
[8]  
Howell J. O., 1987, CURR SEP, V8, P2
[9]  
Murphy G. M., 1960, ORDINARY DIFFERENTIA
[10]   MEASUREMENT OF ULTRAFAST ELECTRODE-KINETICS VIA STEADY-STATE VOLTAMMOGRAMS AT MICRODISC ELECTRODES [J].
OLDHAM, KB ;
ZOSKI, CG ;
BOND, AM ;
SWEIGART, DA .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 248 (02) :467-473