RUTHENIUM-CATALYZED ENANTIOSELECTIVE HYDROGENATION OF 1,3-O-DISUBSTITUTED 1,3-DIHYDROXYPROPAN-2-ONES

被引：10

作者：

CESAROTTI, E ^{[1
]}

ANTOGNAZZA, P ^{[1
]}

MAURI, A ^{[1
]}

PALLAVICINI, M ^{[1
]}

VILLA, L ^{[1
]}

机构：

[1] UNIV MILANO,IST CHIM FARMACEUT & TOSSICOL,I-20131 MILAN,ITALY

来源：

HELVETICA CHIMICA ACTA | 1992年 / 75卷 / 08期

关键词：

D O I：

10.1002/hlca.19920750811

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optically active 1,3-0-disubstituted glycerols were obtained by enantioselective homogeneous hydrogenation of the corresponding 1,3-0-disubstituted 1,3-dihydroxypropan-2-ones with different Ru(II)-binap complexes. The highest enantioselectivities were obtained with dimeric chloro-ruthenium complexes on the -substrates bearing bulky trityloxy groups.

引用

页码：2563 / 2571

页数：9

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