THE SMI2 MEDIATED CROSS-COUPLING REACTION OF ALDEHYDES WITH ALPHA-DIKETONES IN THEIR AQUEOUS FORMS

被引：15

作者：

MIYOSHI, N

TAKEUCHI, S

OHGO, Y

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 12期

关键词：

D O I：

10.1246/cl.1993.2129

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the use of samarium diiodide (SmI2), a cross-coupling reaction of aldehydes with alpha-diketones smoothly proceeds in the presence of water to give the corresponding adducts in moderate to good yield. In this reaction, it is possible to use the substrates such as phenylglyoxal monohydrate, aqueous methylglyoxal, formalin, and aqueous alpha-chloroacetaldehyde.

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页码：2129 / 2132

页数：4

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