REACTIONS OF N,N-BIS(TRIFLUOROMETHYL)HYDROXYLAMINE WITH SULFUR AND NITROGEN HALIDES

被引:13
作者
LOTT, JA
BABB, DP
PULLEN, KE
SHREEVE, JM
机构
[1] Department of Chemistry, University of Idaho, Moscow
关键词
D O I
10.1021/ic50070a026
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A study of the reactions of (CF3)2NOH with several sulfur- and nitrogen-containing halides in the presence of cesium fluoride has resulted in the preparation and characterization of several previously unreported compounds of the general formula (CF3)2NOX where X = SO2F, SO3N(CF3)2, S(0)0N(CF3)2, SON(CF3)2, S(O)F, and SSON(CF3)2. These have been iso¬lated and identified by infrared, nmr, and mass spectra, molecular weight determinations, and elemental analyses. An un¬stable compound of the formula (CF3)2NONF2 is reported as is a convenient method for the preparation of (CF3)2NON-(CF3)2. © 1968, American Chemical Society. All rights reserved.
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页码:2593 / &
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