[RH(4,7-ME2PHEN)2CL2]CL.2H2O - VERY ACTIVE CATALYST IN HYDROGEN TRANSFER-REACTIONS

被引：39

作者：

ZASSINOVICH, G

MESTRONI, G

CAMUS, A

机构：

[1] Istituto di Chimica, Università di Trieste

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 168卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)83284-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of the type [RhChelHx]PF6 and [Rh(Chel)2Cl2]Cl (Chel = Bipy; Phen; 4,4′-Me2Bipy; 4,7-Me2Phen; Hx = 1,5-hexadiene) are very active catalysts in hydrogen transfer from isopropanol to cyclic ketones. The highest rate and stereoselectivity are observed with [Rh(4,7-Me2Phen)2Cl2]Cl. © 1979.

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页码：C37 / C38

页数：2

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