THE ROLE OF METAL-OXIDES IN PROMOTING A COPPER CATALYST FOR METHANOL SYNTHESIS

被引：146

作者：

FUJITANI, T

SAITO, M

KANAI, Y

KAKUMOTO, T

WATANABE, T

NAKAMURA, J

UCHIJIMA, T

机构：

[1] RES INST INNOVAT TECHNOL EARTH,TSUKUBA,IBARAKI 305,JAPAN

[2] UNIV TSUKUBA,INST MAT SCI,TSUKUBA,IBARAKI 305,JAPAN

来源：

CATALYSIS LETTERS | 1994年 / 25卷 / 3-4期

关键词：

METHANOL SYNTHESIS; COPPER CATALYST; OXYGEN COVERAGE;

D O I：

10.1007/BF00816307

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The coverage of oxygen formed on the surface of catalysts during methanol synthesis from CO2 has been measured for copper-based catalysts including various metal oxides using a method called reactive frontal chromatography (RFC). An excellent correlation between the specific activity for methanol synthesis and the oxygen coverage (THETA) was obtained, where the activity increased linearly with oxygen coverage at THETA < 0.16 and then decreased at THETA > 0.18. The results strongly indicate that the support effect or addition of metal oxides revealed in methanol synthesis over copper catalysts is ascribed to the ratio of Cu+ to Cu0 on the surface of copper particles.

引用

页码：271 / 276

页数：6

共 24 条

[1] THE MECHANISM OF METHANOL SYNTHESIS ON COPPER-ZINC OXIDE ALUMINA CATALYSTS [J].