SYNTHESIS AND STRUCTURE SF 2,4,5-TRITHIA-1,3-DISILABICYCLO[1.1.1]PENTANE

被引：18

作者：

CHOI, N ^{[1
]}

ASANO, K ^{[1
]}

ANDO, W ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 07期

关键词：

D O I：

10.1021/om00007a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first 1,3-bis{tris(trimethylsilyl)methyl}-2,4,5-trithia-1,3-disilabicyclo[1.1.1]pentane (2-S3) was prepared by desulfurization of the corresponding 2,4,5,6-tetrathia-1,3-disilabicyclo[2.1.1]hexane (2-S4). The X-ray analysis clearly proved that the distance between the bridgehead silicon atoms of 2-S3 is 2.407 Angstrom, which Lies within the range of common Si-Si single bonds.

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页码：3146 / 3148

页数：3

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