RADICAL CHLORINATION OF SUBSTITUTED T-BUTYLBENZENES

被引：11

作者：

HARVEY, L

GLEICHER, GJ

TOTHEROW, WD

机构：

[1] Department of Chemistry, Oregon State University, Corvallis

来源：

TETRAHEDRON | 1969年 / 25卷 / 20期

关键词：

D O I：

10.1016/S0040-4020(01)83250-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of substituted t-butylbenzenes has been treated with sulfuryl chloride in the presence of benzoyl peroxide at 70°. For six of these compounds, the favored reaction was formation of a substituted neophy radical. While a correlation of data is obtained by application of the Hammett equation, the results may be better described by a field effect approach using a modified Kirkwood-Westheimer treatment. © 1969.

引用

页码：5019 / &

共 41 条

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