TREATMENT OF DEGENERACIES IN SCHRODINGER PERTURBATION THEORY BY PARTITIONING TECHNIQUE

被引:24
作者
CHOI, JH
机构
[1] Department of Chemistry, University of Alberta, Edmonton, Alta.
关键词
D O I
10.1063/1.1664814
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The degenerate case in the Schrödinger perturbation theory has been treated by use of the partitioning technique developed by Löwdin. In order to simplify the concept and treatment, the repeated partitioning technique is utilized. This repeated partitioning allows us to use a one-dimensional reference space and to determine the correct zero-order wavefunction φΔ.
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页码:2142 / &
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