BIOMIMETIC CATALYSTS FOR SELECTIVE OXIDATION IN ORGANIC-CHEMISTRY

被引:165
作者
MANSUY, D
机构
[1] Laboratoire de Chimie et Biochimie Phannacologiques et Toxicologiques, URA 400 CNRS, Universite Rene Descartes, 75270, Paris, Cedex, 06
关键词
D O I
10.1351/pac199062040741
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Major advances have been made towards efficient catalytically active model systems for cytochrome P-450 during these last ten years. Some recent developments of this field are described. This include (i) examples of application of these biomimetic systems to compounds of biological interest, (ii) the use of Mn-porphyrins to catalyze the transfer of a nitrogen atom into organic substrates, and (iii) the preparation and catalytic properties of metalloporphyrins supported on mineral matrices. © 1990, IUPAC.
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页码:741 / 746
页数:6
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