FREE-ELECTRON ATTACHMENT TO VANDERWAALS CLUSTERS

被引：67

作者：

MARK, TD

机构：

[1] Institut für Ionenphysik, Leopold Franzens Universität, A 6020 Innsbruck

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1991年 / 107卷 / 02期

关键词：

ION PHOTOELECTRON-SPECTROSCOPY; NEGATIVELY CHARGED WATER; HYDRATED ELECTRON; MOLECULAR CLUSTERS; AMMONIA CLUSTERS; EXCESS ELECTRONS; SIZE DEPENDENCE; CARBON-DIOXIDE; RYDBERG ATOMS; SO2; CLUSTERS;

D O I：

10.1016/0168-1176(91)80055-R

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The mode of electron interaction (attachment) changes drastically when going from an isolated molecule to a cluster consisting of these molecules. It is the purpose of this review to focus on electrons in clusters and in particular to summarize differences between a negatively charged isolated molecule and its aggregated counterpart. First the physical properties of negative cluster ions (electron affinity, electronic states) and then the kinetics of free electron attachment (attachment cross-sections) will be presented for the van der Waals clusters studied so far.

引用

页码：143 / 163

页数：21

共 79 条

[1] PHOTODISSOCIATION OF MASS-SELECTED (CO2)N-CLUSTERS - EVAPORATION LEADING TO MAGIC NUMBERS IN FRAGMENT-ION DISTRIBUTIONS [J].