THE TRIPLET BIRADICAL TRIS(3,5-DI-TERT-BUTYL-4-OXOPHENYLENE)METHANE - CRYSTAL-STRUCTURE, AND SPIN AND CHARGE-DISTRIBUTION

被引：43

作者：

BOCK, H

JOHN, A

HAVLAS, Z

BATS, JW

机构：

[1] CZECHOSLOVAK ACAD SCI, INST ORGAN CHEM & BIOCHEM, CS-16610 PRAGUE 6, CZECHOSLOVAKIA

[2] UNIV FRANKFURT, INST ORGAN CHEM, W-6000 FRANKFURT 50, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1993年 / 32卷 / 03期

关键词：

D O I：

10.1002/anie.199304161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first structurally characterized triplet ompound. has approximate D3 symmetry with ''propeller blades'' of quinoidally distorted six-membered rings twisted in the same direction (picture on the right). According to calculations the spin and charge distributions differ considerably from one another. Organic triplet diradicals are of interest for the development of molecular ferromagnets. [GRAPHICS]

引用

页码：416 / 418

页数：3

共 25 条

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