Stimulated Raman spectra from H2O, D2O, HDO, and solutions of NaClO4 in H2O and D2O

被引：46

作者：

Colles, M. J. ^{[1
]}

Walrafen, G. E. ^{[1
]}

Wecht, K. W. ^{[1
]}

机构：

[1] Bell Telephone Labs Inc, Murray Hill, NJ USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 4卷 / 10期

关键词：

D O I：

10.1016/0009-2614(70)80100-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Stimulated Raman spectra were obtained from H2O, D2O, H2O-D2O mixtures, and solutions of NaClO4 in H2O and D2O using picosecond pulse excitation at 530.0 nm. The stimulated emission peaks could be predicted from the spontaneous Raman contour shapes for the OD stretching vibrations. but exclusive stimulation of either hydrogen-bonded or of nonhydrogen-bonded components was observed for the OH stretching vibrations. The large widths of the stimulated spectra are discussed in relation to self-focusing and refractive index modulation.

引用

页码：621 / 624

页数：4

共 17 条

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