MECHANISM OF THE RADICAL CO-POLYMERIZATION OF METHYL-METHACRYLATE AND MALEIC-ANHYDRIDE

被引:13
作者
CAZE, C
LOUCHEUX, C
机构
[1] Laboratoire de Chimie Macromolculaire, Universit des Sciences et Techniques, F 59650 Villeneuve d'Ascq
来源
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1978年 / A12卷 / 10期
关键词
D O I
10.1080/00222337808069414
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The kinetics of the copolymerization of methyl methacrylate and maleic anhydride was investigated in benzenic solutions at 60 and 70° C and in bulk at 60°C. The microstructure of the copolymers was determined by ‘H-NMR and IR spectrophotometry. In benzene solutions the mechanism of copolymerization involves the participation of an associative species between both comonomers. In bulk a terminal model is sufficient to explain all the results. © 1978, Taylor & Francis Group, LLC. All rights reserved.
引用
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页码:1501 / 1512
页数:12
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