ELECTRONIC EFFECTS EXERTED IN THE THERMOLYSIS OF 2-OXETANONE - HAMMETT STUDIES OF THE 3-ARYL AND 4-ARYL DERIVATIVES

被引：18

作者：

IMAI, T ^{[1
]}

NISHIDA, S ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC SCI,DEPT CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 20期

关键词：

D O I：

10.1021/jo01334a028

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In spite of the widespread interest in the mechanism of the 2-oxetanone thermolysis, 1 only scanty reports describing the quantitative investigations of such reactions are available.1b, e As a result, the electronic effects exerted by the substituent at the C-3 or C-4 position have not yet been clarified.2. © 1979, American Chemical Society. All rights reserved.

引用

页码：3574 / 3576

页数：3

共 26 条

[1] STEREOSPECIFIC INTRODUCTION OF DOUBLE-BONDS VIA THERMOLYSIS OF BETA-LACTONES [J].

ADAM, W ;

BAEZA, J ;

LIU, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (06) :2000-&

[2] THE GRIGNARD REAGENT IN HYDROCARBON SYNTHESIS [J].

BOORD, CE ;

HENNE, AL ;

GREENLEE, KW ;

PERILSTEIN, WL ;

DERFER, JM .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1949, 41 (03) :609-616

[3] DECARBOXYLATION OF HALOGENATED 2-OXETANONES [J].

BRADY, WT ;

PATEL, AD .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (22) :3536-&

[4] DIRECTIVE EFFECTS IN AROMATIC SUBSTITUTION .30. ELECTROPHILIC SUBSTITUENT CONSTANTS [J].

BROWN, HC ;

OKAMOTO, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (18) :4979-4987

[5] DIRECTIVE EFFECTS IN AROMATIC SUBSTITUTIONS .14. SUBSTITUENT CONSTANTS FOR AROMATIC SUBSTITUTION [J].

BROWN, HC ;

OKAMOTO, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (08) :1913-1917

[6] PHOTOISOMERIZATION OF SUBSTITUTED ACRYLIC ACIDS AND ACRYLAMIDES TO BETA-LACTONES AND BETA-LACTAMS [J].

CHAPMAN, OL ;

ADAMS, WR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (09) :2333-&

[7]

DULTON GGS, 1953, CAN J CHEM, V31, P1138

[8] KINETICS OF GAS-PHASE THERMAL UNIMOLECULAR ELIMINATION OF KETENE OR 1,1-DIMETHYLKETENE FROM 2,2-DIMETHYL-3-ETHOXYCYCLOBUTAN-1-ONE - QUASI-ZWITTERION TRANSITION-STATE [J].

EGGER, KW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (06) :1745-1750

[9] THERMAL DECOMPOSITION OF BETA-PROPIOLACTONE IN GAS PHASE [J].

JAMES, TL ;

WELLINGT.CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (27) :7743-&

[10] BETA-SULTINES - INTERMEDIATES IN A SULFUR ANALOG OF WITTIG OLEFIN SYNTHESIS [J].

JUNG, F ;

SHARMA, NK ;

DURST, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (10) :3420-3422

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