DIOLATES OF DIMOLYBDENUM AND DITUNGSTEN (M=M) WITH 7-MEMBERED, 8-MEMBERED AND 9-MEMBERED RINGS

被引：20

作者：

CHISHOLM, MH ^{[1
]}

PARKIN, IP ^{[1
]}

FOLTING, K ^{[1
]}

LUBKOVSKY, EB ^{[1
]}

STREIB, WE ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 23期

关键词：

D O I：

10.1039/c39910001673

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of the bulky diols, H2L1 = 2,5-dimethylhexane-2,5-diol and H3L2 = 2,2'-methylenebis(6-tert-butyl-p-cresol) in reactions with M2(NMe2)6 (M = M) compounds leads to dinuclear diolates M2(L1)3(HNMe2)2 1, M2(L1)3 2, Mo2(NMe2)2-(HL2) 3 having seven-, eight- and nine-membered rings and W2(mu-H)(mu-NMe2)(NMe2)(HNMe2)(HL2)(L2), 4, where L2 is the anionic ligand derived from cyclometallation at the methylene carbon atom; the compounds 1 and 2 where M = W, 3, and 4 have been structurally characterized.

引用

页码：1673 / 1675

页数：3

共 6 条

[1]

BASOLO F, 1968, INORGANIC REACTION M

[2] ORGANOMETALLIC CHEMISTRY OF D3-D3 DIMOLYBDENUM AND DITUNGSTEN [J].

CHISHOLM, MH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 400 (1-2) :235-253

[3] METAL METAL BONDS AND METAL-CARBON BONDS IN THE CHEMISTRY OF MOLYBDENUM AND TUNGSTEN ALKOXIDES [J].

CHISHOLM, MH .

POLYHEDRON, 1983, 2 (08) :681-722

[4] THE COORDINATION CHEMISTRY OF DINUCLEAR MOLYBDENUM(III) AND TUNGSTEN(III) - D3-D3 DIMERS [J].

CHISHOLM, MH .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (12) :419-425

[5] DEVELOPING THE REACTIVITY OF MULTIPLE BONDS BETWEEN METAL ATOMS - INORGANIC FUNCTIONAL-GROUPS [J].

CHISHOLM, MH .

PURE AND APPLIED CHEMISTRY, 1991, 63 (05) :665-680

[6]

Cotton F.A, 1982, MULTIPLE BONDS METAL

← 1 →