DINUCLEAR MANGANESE(II) COMPLEXES WITH WATER AND CARBOXYLATE BRIDGES

被引：110

作者：

YU, SB

LIPPARD, SJ

SHWEKY, I

BINO, A

机构：

[1] MIT, DEPT CHEM, CAMBRIDGE, MA 02139 USA

[2] HEBREW UNIV JERUSALEM, DEPT INORGAN & ANALYT CHEM, IL-91904 JERUSALEM, ISRAEL

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 17期

关键词：

D O I：

10.1021/ic00043a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two (mu-aqua)bis(mu-carboxylato)dimanganese(II) complexes with oxygen and nitrogen donor ligands have been synthesized. Crystal structure determinations reveal a distance of 3.6 angstrom between the two manganese atoms. Magnetic studies indicate weak antiferromagnetic exchange between the two Mn centers with a coupling constant of approximately -2 to -3 cm-1.

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页码：3502 / 3504

页数：3

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