CONVERSION OF NITRIC-OXIDE INTO A NITROXIDE RADICAL USING 2,3-DIMETHYLBUTADIENE AND 2,5-DIMETHYLHEXADIENE

被引：19

作者：

GABR, IM ^{[1
]}

RAI, US ^{[1
]}

SYMONS, MCR ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期

关键词：

D O I：

10.1039/c39930001099

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of nitric oxide with 2,3-dimethyl-1,3-butadiene gave an unstable nitroxide radical characterised by hyperfine coupling to four equivalent beta-protons in addition to the normal N-14 triplet: however reaction with the tetramethyl derivative (2,5-dimethyl-2,4-hexadiene) gave an extremely stable nitroxide, which may be of use in pollution studies and especially in studies of nitric oxide in mammalian cells.

引用

页码：1099 / 1100

页数：2

共 9 条

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