REACTIONS OF THE MO=S BOND IN THE [(CP)MO(O)(MU-S)2MO(O)(S)]- COMPLEX WITH SO2 - AN H-1-NMR STUDY AND THE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(CP)MO(O)(MU-S)2MO(O)(L)]- COMPLEXES CONTAINING SO2-DERIVED SULFITE, THIOSULFATE, AND SULFATE BIDENTATE CHELATING LIGANDS

被引：16

作者：

KIM, CG ^{[1
]}

COUCOUVANIS, D ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 10期

关键词：

D O I：

10.1021/ic00062a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the Mo=S unit in the [(Cp)Mo(O)(mu-S)2Mo(O)(S)]- complex with SO2 at various temperatures give various products of the type [(CP)Mo(O)(mu-S)2Mo(O)(L)]- (L = SO32-, S2O32- , and SO42-). A H-1-NMR study of these reactions indicates that the final products isolated and structurally characterized are derivatives of the unstable [(Cp)Mo(O)(mu-S)2Mo(O)(S2O2)]-complex that forms initially by SO2 addition to the Mo=S unit and undergoes further reactions with SO2.

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页码：1881 / 1882

页数：2

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