[(ETA(6)-BENZOCROWN ETHER)CR(CO)(3)], COMPLEXES AS FTIR-READABLE MOLECULAR SENSORS FOR ALKALI-METAL CATIONS

被引：33

作者：

ANSON, CE

CREASER, CS

STEPHENSON, GR

机构：

[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

[2] NOTTINGHAM TRENT UNIV,DEPT CHEM & PHYS,NOTTINGHAM NG11 8NS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The upsilon(CO) modes of [(eta(6)-benzocrown ether)Cr(CO)(3)] complexes in methanol and methanol-water solutions shift to higher wavenumber with addition of alkali metal salts to the solution; this wavenumber shift correlates with the cation concentration such that the complexes can be used as molecular sensors for the metal cations.

引用

页码：2175 / 2176

页数：2

共 15 条

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