METAL-ALKYL AND METAL-ARYL COMPOUNDS .45. DECAMERIC AND DODECAMERIC SODIUM AMIDES AND AN ORGANOSODIUM AMIDE WITH STACK STRUCTURES - [NA10(NME2)10(TMEDA)4], [NA12(NME2)12(TMEDA)4], AND [NA12(NME2)10(CH2C6H4ME)2(TMEDA)4]

被引：25

作者：

LORENZEN, NP ^{[1
]}

KOPF, J ^{[1
]}

OLBRICH, F ^{[1
]}

SCHUMANN, U ^{[1
]}

WEISS, E ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,MARTIN LUTHER KING PL 6,W-2000 HAMBURG 13,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oligomeric sodiumamides 1-3, which were formed during attempts to metalate hydrocarbons with n-butylsodium in the presence of teteramethylethylene-diamine, have stacked ring structures. Correspondingly structured lithium amides are not known; rather, in this case ladder structures should be preferred.

引用

页码：1441 / 1444

页数：4

共 22 条

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