LINEAR SOLVATION ENERGY RELATIONSHIPS .1. SOLVENT POLARITY - POLARIZABILITY EFFECTS ON INFRARED-SPECTRA

被引：93

作者：

KAMLET, MJ ^{[1
]}

TAFT, RW ^{[1
]}

机构：

[1] UNIV CALIF IRVINE, DEPT CHEM, IRVINE, CA 92717 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1979年 / 03期

关键词：

D O I：

10.1039/p29790000337

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The linear solvation energy relationship (LSER) concept is shown to apply to i.r. spectra. Solvatochromic shifts of a variety of X = O, C-Cl, and O-H ⋯ B stretching frequencies and solvent effects on absorption intensities are linear with solvent π*-values. Values of s in the solvatochromic equation, v̄ = v̄0 + sπ*, are related to chromophore structures.

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页码：337 / 341

页数：5

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